Scanning probe workstations

M470.

Modular scanning electrochemistry

A modular, state-of-the-art instrument allowing users to exploit 9 local electrochemistry techniques.

All scanning probe electrochemistry techniques are characterized by their visualization of local electrochemical characteristics. Unlike bulk electrochemical measurements, which provide an average of the electrochemical nature of a sample, scanning probe electrochemistry allows the correlation of sample features and their electrochemistry. This can provide users with further insight into the causes of the electrochemistry they see in the bulk system. Furthermore, users can understand how different sample features, like step edges, and grain boundaries affect the bulk electrochemistry.

Scanning Probe Electrochemistry on the M470

Scanning probe electrochemistry encompasses a range of techniques, which provide complementary information. The M470 can perform Scanning Electrochemical Microscopy (SECM), Intermittent Contact-SECM (ic-SECM), Localized Electrochemical Impedance Spectroscopy (LEIS), Scanning Vibrating Electrode Technique (SVET) (also known as vibrating probe), Scanning Kelvin Probe (SKP), Scanning Droplet Cell (SDC) and Optical Surface Profiling (OSP). Through a selection of the different modules a researcher can investigate:

  • Surface activity
  • Local impedance
  • Local potential
  • Local current
  • Topography

The combination of these allows a complete description of the sample under study to be obtained.

Scanning probe electrochemistry has found use in any field in which researchers would like to further understand the factors contributing to the bulk electrochemistry measured. It has been firmly established in corrosion research, with the particular aim of understanding where and how corrosion processes start. In corrosion research, scanning electrochemical techniques are also used to determine the effectiveness of a treatment or coating and how improvements can be made to further passivate a system. In biology, scanning probe electrochemistry has been used to investigate living cells and particular emphasis has been placed on its use in screening biosensors. In the energy sector scanning probe electrochemistry has found use investigating batteries, fuel cells and photovoltaics. Materials science also benefits from the use of scanning probe electrochemistry, which has even been used to investigate 2D materials.

Overview: A fully modular instrument for a completely customizable scanning probe electrochemistry experience.

  • 9 techniques from 7 modules
  • Full range of accessories to tailor the experimental setup
  • 110 mm scan range on all 3 axes
  • Constant height and constant distance measurements available

Completely modular and upgradable

The M470 is the fourth generation scanning probe electrochemistry instrument available from Bio-Logic. Building on previous generations the M470 offers the highest level of flexibility yet. Users can select from seven different module types to perform nine different scanning probe techniques. This gives users a range of information from topography to electrochemical activity to sample current. The M470 adapts dynamically to the needs of researchers. Its modular nature means users can add further techniques, as and when experimental needs arise. All module electronics fit within the same control unit allowing users to grow their technique catalog without growing the spatial requirements of the instrument. A full range of probes and accessories is also available for users to fine-tune the M470 to meet their experimental needs.

Scanning stage…. High Resolution and High Accuracy

The M470 scanning stage has been designed for scanning probe electrochemistry measurements. This means high resolution and high accuracy measurements. The movement of the scanning stage is highly repeatable without hysteresis. It maintains rectilinear movement, meaning the stage will not undergo twisting out of the axis of movement.  Cross talk between the three axes is avoided. The M470 uses a closed-loop positioning system. The combination of these elements allows the M470 scanning stage to achieve high resolution and high accuracy measurements which do not show artifacts due to the positioning system.

The software allows experiment design through the use of sequencing and Macros

Not every experiment is the same. Keeping this in mind, the M470 software provides a number of tools to allow users to design their experiment. With the Experiment Sequence option, users can automatically run a series of experiments and logic steps. This gives users access to all of the experiments available to their M470, as well as scanning stage movements and delays. Custom experiments can also be written for the M470 using its fully programmable macro language. Finally, the Modular Map SECM experiment allows users of the SECM470 greater flexibility in their experimental configuration.

 

Techniques Available

SECM470

The SECM470 module includes both dc-SECM and ac-SECM techniques. dc-SECM uses a redox mediator to measure local electrochemical activity of the sample at a constant height. ac-SECM also measures the local activity of the sample at a constant height. Because impedance is now measured a redox mediator is not needed. ac-SECM may also be used to measure individual EIS spectra

ic-SECM470

ic-SECM470 includes both ic-dc-SECM and ic-ac-SECM. With the ic-SECM470 option, the user can measure the local sample activity and topography with chemical selectivity with a constant distance between the probe and sample. Through a single experiment, the user obtains both a sample activity and a sample topography map.

LEIS470

LEIS470 allows both LEIS and Local Electrochemical Impedance Microscopy (LEIM) measurements. In LEIS point-by-point impedance spectra are measured. When LEIM is used local impedance differences can be mapped in x,y at a single ac frequency.

SVP470

SVP470 performs the Scanning Vibrating Electrode Technique (SVET)/Vibrating Probe experiments. In SVET the local current distribution of a sample in electrolyte is measured.

SKP470

SKP470 performs the SKP experiments. Using SKP the Volta potential , which is directly related to the sample work function of a sample can be measured without contact or exposure to the electrolyte. SKP470 also includes two topography techniques for use in constant distance SKP measurements.

SDS470

Using the SDS470 module ac- and dc-SDC measurements can be performed. Using SDC direct electrochemical and impedance measurements can be performed within a droplet, which can also move across a surface.

OSP470

The OSP470 module makes use of the diffracted light of a laser beam to perform OSP measurements. As such OSP is a non-contact, high speed, topography measurement. Results from the OSP470 measurements can be used in all M470 height tracking measurements to allow constant distance measurements.

Workstation Software

The Scanning Electrochemical Workstation software provides unique capabilities and interactivity in support of the Model 370 and Model 470 nanometer-resolution scanning probe microscopes. This highly ergonomic software has been designed to facilitate and improve the user experience and render work flows more efficient:

  • Improved data analysis, manipulation and interactivity
  •  Automatic measurement and sequencing functionalities.

Over 40 discrete experiments provided throughout, each with their own individual variations

Specifications

Scanning Stage

SP-300
Compliance Voltage ±12 V
Applied Potential ±10 V
Resolution 300 µV
Measured Potential ±10 V
Resolution 1.65 µV
Current Ranges 100 pA to 1A
Maximum Current ± 500 mA
Current Resolution 76 aA
Floating Capability Floating Mode
Cell Connections 2, 3, or 4 electrode
Scan Rate 1 µV/s to 200 V/s
Modes Potentiostat, Galvanostat, OCP
EIS Capability
Frequency Range 10 µHz to 3 MHz
Analyzer Accuracy 1%, 1°
Frequency Resolution 0.1 nHz
Available Experiments Chronoamperometry, Chrono OCP, Chronopotentiometry, Cyclic Voltammetry, Differential Pulse Voltammetry, Normal Pulse Voltammetry, Linear Voltammetry, Square Wave Voltammetry, ECorr vs Time,  Galvanostatic Polarization, Linear Polarization Resistance, Potentiodynamic Polarization, Potentiostatic Polarization, Tafel, Zero Resistance Ammetry, Electrochemical Impedance Spectroscopy

 

3300
Compliance Voltage ±12 V
Applied Potential ±10 V
Resolution 4.7 nV
Measured Potential ±10 V
Resolution 1.2 µV
Current Ranges 1 nA to 1A
Maximum Current ± 500 mA
Current Resolution 23.8 fA
Floating Capability Standard
Cell Connections 2, 3, or 4 electrode
Scan Rate 1 µV/s to 200 V/s
Modes Potentiostat, Galvanostat, OCP
EIS Capability
Frequency Range 1 µHz to 1 MHz
Analyser Accuracy 0.1%, 1°
Frequency Resolution 66 nHz
Available Experiments Chronoamperometry, Chrono OCP, Chronopotentiometry, Cyclic Voltammetry, Differential Pulse Voltammetry, Normal Pulse Voltammetry, Linear Voltammetry, Square Wave Voltammetry, ECorr vs Time,  Galvanostatic Polarization, Linear Polarization Resistance, Potentiodynamic Polarization, Potentiostatic Polarization, Tafel, Zero Resistance Ammetry, Electrochemical Impedance Spectroscopy

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