Hydrogen reference electrodes - BioLogic

Electrode

Hydrogen reference electrodes

Hg-free electrodes for demanding experiments

HydroFlex® and MiniHydroFlex® are robust, easy-to-use Reversible Hydrogen Electrodes (RHE) suitable for any application.

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These reference electrodes are designed for any application involving electrochemistry. Their PTFE body makes them particularly suitable for the most demanding conditions and operating conditions: protic solvents, corrosive electrolytes, high temperatures…They also provide the advantage of being Hg-free, following RoHS recommendations.

 

Benefits of Reversible Hydrogen Electrodes (RHE)

  • Mercury free
  • Good for EIS
    • Resistance typically around 1 Ohm, whereas it is between 1 kOhm and 10 kOhm for traditional electrodes
  • No contamination
    • Outlet of inner reference electrolyte (KCl, K2SO4, Hg+, Ag+) into test electrolyte. May contaminate your test liquid or introduce corrosion
  • Wide pH (-2 to 16) and temperature range (-20 to 210 °C)
  • Not sensitive to temperature or pH changes
    • The temperature of RE and WE can differ, as they are in two different liquids (reference electrolyte and test electrolyte).
    • pH effect on potential of working electrode has to be take into account. In the case of potential and pH changes during measurement continuous pH measurement essential
  • No maintenance
    • Reference electrolyte has to be controlled regularly.
  • Not breakable
    • Reference made usually out of glass (risk of breakage)
  • No frit
    • Frit between reference and test electrolyte may fall out, get blocked, change during life time, let test electrolyte into the reference electrolyte.

 

HydroFlex® and MiniHydroFlex®.

 

The HydroFlex®, with an electrode shaft diameter OD of 8 mm, is compatible with EL-ELECTRO, EL-CORR, EL-FLAT cells using dedicated bridge tubes (see specification tab).

Both HydroFlex® and MiniHydroFlex® are compatible with Gaskatel voltammetric cells, FlexCell® also provided by BioLogic.

 

Hydrogen is contained within a cartridge that is easily replaceable. On the left, the HydroFlex®, and on the right, the MiniHydroFlex®.

 

 

DescriptionCatalog n°
HydroFlex® Hydrogen Reference Electrode incl. one hydrogen cartridgeG-HYDROFLEX
HydroFlex® Starter KitG-HYDROFLEX-KIT
MiniHydroFlex® Hydrogen Reference Electrode incl. one hydrogen cellG-MINIHYDROFLEX
Options
HydroFlex® Hydrogen Cartridge (x4)G-HYDROFLEX-CARTRIDGE
MiniHydroFlex® Hydrogen Cell (x2)G-MINIHYDRO-CELL
Bridge tube for use of HydroFlex® with EL-ELECTROEL-A-017
Bridge tube for use of HydroFlex® with EL-CORREL-C-017
Bridge tube for use of HydroFlex®with EL-FLATEL-F-004b
Operating conditions
Cartridge lifetime/months12 (MiniHydroFlex®), 6 (HydroFlex®)
Temperature/°C-20 to 120 (PTFE body)
pH range -2 to 16
Part Materials
BodyPTFE, PP
ShaftPEEK, PTFE
Cap and cartridgePC or PVC
Measuring electrodePt, Pd
HydroFlex® Starter Kit Content
1 HydroFlex® Hydrogen reference electrode incl. 1 hydrogen cartridge
1 connector lead
1 hydrogen cartridge
1 cartridge wrench
1 operating time wrench